Əsas səhifəJurnallarTədqiqatçılarElanlarƏlaqə
|
☰

NAXÇIVAN DÖVLƏT UNİVERSİTETİNİN ELMİ ƏSƏRLƏRİ

Ce2Se3-Sb2Se3-Bi2Se3 KVAZİÜÇLÜ SİSTEMİNDƏ FAZAƏMƏLƏGƏLMƏ

S.H.Məmmədova
F.M.Sadıqov

İl: 2024 | Cildlər: 6 |Səhifə: 101-108

Xülasə

Based on the literature data, as well as the results obtained by the methods of physicochemical analysis, the character of phase formation in the Ce2Se3-Sb2Se3-Bi2Se3 quasi-ternary system was determined. The phase diagrams of a number of internal sections (Sb2Se3-CeBiSe3, Ce2Se3-CeSb1,5Bi1,5Se6, Bi2Se3-CeSb1,5Bi1,5Se6, CeSbSe3 -CeBiSe3), the isothermal section at 300 K, and the projection of the liquidus surface were constructed, the types and coordinates of non- and monovariant equilibria were obtained. The existence of six ternary compounds, S1(Ce8Sb2Se15), S2(Ce6Sb4Se15), S3(CeSbSe3), S4 (CeBiSe3), S5( CeSb1,5Bi1,5Se6 ) and S6 (Ce8Bi2Se13), as well as regions of solid solutions based on the initial Sb2Se3 , Bi2Se3 , as well as S5 compounds was shown.

article.keywords: antimony and bismuth chalcogenides, REE chalcogenides, quasi-binary section, nonquasi-binary section, liquidus surface projections

İstinadlar -

  1. Baghbanzadeh-Dezfuli, B., Jamali-Sheini, F., Cheraghizade, M. Sonical deposition of nanostructured Sb2Se3 films for optoelectronic applications // Journal of Alloys and Compounds, 2021, v.25, p. 157308
  2. Wang, F.K., Yang, S.J., Zhai, T.Y. 2D Bi2Se3 materials for optoelectronics // IScience, 2021,v.24, Issue 11, p.103291
  3. Ghosh, S., Moreira, M.V.B., Fantini, C., González, J.C. Growth and optical properties of nanocrystalline Sb2Se3 thin-films for the application in solar-cells // Solar Energy, 2020, v. 211, p.613-621
  4. Venkatasubramanian, R., Siivola, E., Colpitts, T., O’Quinn B. Thin-film thermoelectric devices with high room-temperature figures of merit // Nature, 2001, v.413, p.597-602
  5. An, D., Chen, S., Lu, Z., Li, R., Chen, W., Fan, W., Wang, W., and Wu, Y. Low Thermal Conductivity and Optimized Thermoelectric Properties of p-Type Te–Sb2Se3: Synergistic Effect of Doping and Defect Engineering // CS Appl. Mater. Interfaces, 2019, v.11, No31, p.27788–27797
  6. Wu,J-K, Hofmann, M., Hsieh, W-P, Chen, S-H., Yen, Z-L., Chiu, S-K., Luo, Y-R., Chiang, C-C., Huang, Y., Huang, S-Y., Chang, Y-H., and Hsieh, Y-P. Enhancing Thermoelectric Properties of 2D Bi2Se3 by 1D Texturing with Graphene // ACS Appl. Energy Mater. 2019, v.2, No.12, p.8411– 8415
  7. Kim, H.C., Oh, T.S., Hyun, D.B. Thermoelectric properties of the p-type Bi2Te3-Sb2Te3- Sb2Se3 alloys fabricated by mechanical alloying and hot pressing. // Journal of Physics and Chemistry of Solids, 2000, v.61(5), p.743-749
  8. Yang, W., Kim, J.H., Hutter, O.S. et al. Benchmark performance of low-cost Sb2Se3 photocathodes for unassisted solar overall water splitting. // Nature Communications, 2020, v. 11, p.861
  9. Sankapal, B.R., Lokhande, C.D. Studies on photoelectrochemical (PEC) cell formed with SILAR deposited Bi2Se3-Sb2Se3 multilayer thin films. // Sol. Energy Mater. Sol. Cell. 2001, v. 69, p.43-52.
  10. Li, W., Deng, L., Wang, X., Cao, J., Xie, Y., Zhang, Q., Zhang, H., Deng, H. and Cheng, S. Close-spaced thermally evaporated 3D Sb2Se3 film for high-rate and high-capacity lithium-ion storage // Nanoscale, 2021, v.13, p.9834-9842
  11. Xue, M.-Z., Fu, Z.-W. Pulsed laser deposited Sb2Se3 anode for lithium-ion batteries // J. Alloys and Compounds, 2008, v.458. p.351-356
  12. Ma, J., Wang, Y., Wang, Y., Chen, Q., Lian, J., Zheng, W., Controlled synthesis of onedimensional Sb2Se3 nanostructures and their electrochemical properties // J. Phys. Chem. C, 2009, v. 113, p.13588-13592
  13. Zhang, H., Liu, C.-X., Qi, X.-L., Dai, X., Fang, Z., Zhang, S.-C. Topological insulators in Bi2Se3, Bi2Te3 and Sb2Te3 with a single Dirac cone on the surface // Nat. Phys., 2009, v. 5, p.438.
  14. Mazumder, K., Shirage, P.M. A brief review of Bi2Se3 based topological insulator: From fundamentals to applications // Journal of Alloys and Compounds, 2021, v.888, p. 161492
  15. Anversa, J., Chakraborty, S., Piquini, P., Ahuja, R. High pressure driven superconducting critical temperature tuning in Sb2Se3 topological insulator // Appl. Phys. Lett., 2016, v. 108, p.212601.
  16. Kong, P.P., Sun, F., Xing, L.Y., Zhu, J., Zhang, S.J., Li, W.M., Liu Q.Q., Wang, X.C., Feng, S.M. et al. Superconductivity in strong spin orbital coupling compound Sb2Se3 // Sci. Rep., 2014, No4, p. 6679
  17. Шурова, М.А, Андреев, О.В, Харитонцев, В.Б. Фазовые равновесия в системе Bi2Se3- Sm2Se3 // Вестник Тюменского Государственного Университета. Социальноэкономические и правовые исследования, 2014, N5, с.113-121
  18. Andreev, O.V., Kharitsontsev, V.B., Elyshev, A.V. Compositions of phrases in the interaction of rare-earth metals with selenium// Russ J.Inorg.Chem., 2013, v.58, p.910
  19. Мамедова, С.Г., Садыгов, Ф.М., Гасымов, В.А. и др. Исследование систем Sb2Se3-CeSe и Bi2Se3-CeSe / Ж. Неорг. Химии, 2003, т.48, N3, c.494-496
  20. Садыгов, Ф.М., Мамедова, С.Г., Бабанлы, М.Б., Ильяслы, Т.М. Фазовые равновесия в системе Ce-Sb-Se по разрезу Sb2Se3-Ce2Se3 // Журн. Неорг. химии, 2001, т.46, N8, с.1382-1383